1 00:00:00 --> 00:00:01 Hello everyone. 2 00:00:02 --> 00:00:06 Welcome the tutorial on Formation of bonds in GChemPaint. 3 00:00:07 --> 00:00:09 In this tutorial, we will learn to- 4 00:00:10 --> 00:00:12 * Add bonds to the existing bond 5 00:00:13 --> 00:00:14 * Orient the bonds 6 00:00:15 --> 00:00:17 * Add Stereochemical bonds and 7 00:00:18 --> 00:00:20 * Inverse wedge hashes. 8 00:00:21 --> 00:00:26 Here I am using Ubuntu Linux OS version. 12.04, 9 00:00:27 --> 00:00:32 GChemPaint version 0.12.10 10 00:00:33 --> 00:00:36 To follow this tutorial you should be familiar with, 11 00:00:37 --> 00:00:39 GChemPaint chemical structure editor. 12 00:00:40 --> 00:00:45 If not, for relevant tutorials, please visit our website. 13 00:00:46 --> 00:00:50 I have opened a new GChemPaint application with Ethane structure. 14 00:00:51 --> 00:00:57 Let us learn to convert Saturated Hydrocarbons to Unsaturated Hydrocarbons. 15 00:00:58 --> 00:01:04 Let us copy the Ethane structure and paste it twice on the Display area. 16 00:01:05 --> 00:01:07 Click on Select one or more objects tool. 17 00:01:08 --> 00:01:10 Click on Ethane structure to select it. 18 00:01:11 --> 00:01:13 Press Ctrl +C to copy the structure 19 00:01:14 --> 00:01:18 and Press Ctrl + V to paste the structures. 20 00:01:19 --> 00:01:22 Observe that two structures overlap each other. 21 00:01:23 --> 00:01:26 Let's move the second overlapping structure aside. 22 00:01:27 --> 00:01:32 Place the cursor on the structure and drag it with the mouse. 23 00:01:33 --> 00:01:39 Observe the single bond between the carbon atoms in the structures. 24 00:01:40 --> 00:01:43 Let's first convert single bond to a double bond. 25 00:01:44 --> 00:01:50 Click on Add a bond or change the multiplicity of an existing one tool. 26 00:01:51 --> 00:01:54 Click on the existing bond of the second Ethane structure. 27 00:01:55 --> 00:01:59 Observe that single bond is converted to a double bond. 28 00:02:00 --> 00:02:05 Number of Hydrogen atoms reduced from 6 to 4. 29 00:02:06 --> 00:02:08 The new structure is Ethene. 30 00:02:09 --> 00:02:13 Next let's convert the single bond to a triple bond. 31 00:02:14 --> 00:02:19 Click on the existing bond of the third Ethane structure twice. 32 00:02:20 --> 00:02:24 Observe that Single bond is converted to a triple bond. 33 00:02:25 --> 00:02:29 Number of hydrogen atoms reduced from 6 to 2. 34 00:02:30 --> 00:02:33 The new structure is Ethyne. 35 00:02:34 --> 00:02:36 Let us write the names of the structures. 36 00:02:37 --> 00:02:40 Click on Add or modify a text tool. 37 00:02:41 --> 00:02:42 Click below the structures. 38 00:02:43 --> 00:02:52 Enter the names of the structures as Ethane, Ethene and Ethyne. 39 00:02:53 --> 00:02:56 Next, let us learn about Tetrahedral geometry. 40 00:02:57 --> 00:02:59 Let's move the structures to a side. 41 00:03:00 --> 00:03:02 Press Ctrl+A to select all objects. 42 00:03:03 --> 00:03:09 Click on Select one or more objects tool and drag the structures. 43 00:03:10 --> 00:03:13 Here is a slide for the Tetrahedral Methane structure. 44 00:03:14 --> 00:03:18 All the bond lengths are equal to 1.09 angstrom. 45 00:03:19 --> 00:03:30 In Tetrahedral methane structure, all the bond angles are equal to 109.5 degree. 46 00:03:31 --> 00:03:34 Now, let's draw Tetrahedral Ethane structure. 47 00:03:35 --> 00:03:40 Click on Add a bond or change the multiplicity of existing one tool. 48 00:03:41 --> 00:03:42 Click on the Display area. 49 00:03:43 --> 00:03:46 Orient the bond in horizontal direction. 50 00:03:47 --> 00:03:50 On each edge of the bond let us draw three bonds. 51 00:03:51 --> 00:03:54 Orient the bonds to form a Tetrahedral geometry. 52 00:03:55 --> 00:04:01 Click on each edge. Then orient the three bonds in different directions. 53 00:04:02 --> 00:04:06 Likewise let us draw on the other edge. 54 00:04:07 --> 00:04:09 Let us attach hydrogen atoms at the ends. 55 00:04:10 --> 00:04:15 To attach Hydrogen atoms to the ends, press capital H. 56 00:04:16 --> 00:04:20 A sub-menu opens in which we will select H. 57 00:04:21 --> 00:04:25 Observe that Hydrogen atom appears in the tool box. 58 00:04:26 --> 00:04:28 Click on Add or modify an atom tool. 59 00:04:29 --> 00:04:36 Click on all the positions to add hydrogen atoms. 60 00:04:37 --> 00:04:41 Now let us add Stereochemical bonds to Ethane structure. 61 00:04:42 --> 00:04:45 Stereochemical bonds available in the tool box are, 62 00:04:46 --> 00:04:47 * Add a wedge bond 63 00:04:48 --> 00:04:49 * Add a hash bond 64 00:04:50 --> 00:04:52 * Add a squiggle bond 65 00:04:53 --> 00:04:54 * and Add a fore bond. 66 00:04:55 --> 00:05:02 Let us use Add a wedge bond to convert Ethane to a "Stereochemical" structure. 67 00:05:03 --> 00:05:04 Click on Add a wedge bond. 68 00:05:05 --> 00:05:09 Then click on all the bonds. 69 00:05:10 --> 00:05:12 Observe the changes. 70 00:05:13 --> 00:05:14 Click on Add a hash bond 71 00:05:15 --> 00:05:18 and then click on the Display area. 72 00:05:19 --> 00:05:24 Now I will explain about Invert wedge hashes. 73 00:05:25 --> 00:05:30 Go to Edit menu, navigate to Preferences and click on it. 74 00:05:31 --> 00:05:33 GChemPaint Preferences window opens. 75 00:05:34 --> 00:05:37 Click on Invert wedge hashes check box. 76 00:05:38 --> 00:05:42 If set, the wedge hashes bonds will follow the usual convention. 77 00:05:43 --> 00:05:49 Narrow end is at the start of the bond and broad end is at the other end. 78 00:05:50 --> 00:05:54 This helps to visualize the bond correctly. 79 00:05:55 --> 00:06:04 Default convention in GChemPaint is inverse, because it is more consistent with the perspective rules. 80 00:06:05 --> 00:06:08 Observe the changes in the Hash bond. 81 00:06:09 --> 00:06:12 Let us click on Close button to close the window. 82 00:06:13 --> 00:06:17 Let us change the bonds to Add a hash bond in the Ethane structure. 83 00:06:18 --> 00:06:20 Click on Add a hash bond. 84 00:06:21 --> 00:06:26 Click on all the bonds. 85 00:06:27 --> 00:06:29 Let us now save the file. 86 00:06:30 --> 00:06:33 Click on Save the current file icon on the toolbar. 87 00:06:34 --> 00:06:36 Save as dialog box opens. 88 00:06:37 --> 00:06:40 Enter the file name as Formation of bond . 89 00:06:41 --> 00:06:43 Click on Save button. 90 00:06:44 --> 00:06:45 Let's summarise. 91 00:06:46 --> 00:06:48 In this tutorial we have learnt to, 92 00:06:49 --> 00:06:51 * Add bonds to the existing bond 93 00:06:52 --> 00:06:53 * Orient the bonds 94 00:06:54 --> 00:06:55 * Add Stereochemical bonds 95 00:06:56 --> 00:06:59 * and Inverse wedge hashes. 96 00:07:00 --> 00:07:00 As an assignment, 97 00:07:01 --> 00:07:03 * Convert Propane to Propyne 98 00:07:04 --> 00:07:06 * Draw Propane and butane structures 99 00:07:07 --> 00:07:10 * Show the stereochemical bonds. 100 00:07:11 --> 00:07:15 Your completed assignment should look like this. 101 00:07:16 --> 00:07:18 Watch the video available at this URL http://spoken-tutorial.org /What_a_Spoken_Tutorial. 102 00:07:19 --> 00:07:22 It summarizes the Spoken Tutorial project. 103 00:07:23 --> 00:07:27 If you do not have good bandwidth, you can download and watch it. 104 00:07:28 --> 00:07:32 The Spoken Tutorial Project Team: Conducts workshops using spoken tutorials. 105 00:07:33 --> 00:07:35 Gives certificates to those who pass an online test. 106 00:07:36 --> 00:07:41 For more details, please write to contact@spoken-tutorial.org. 107 00:07:42 --> 00:07:46 Spoken Tutorial Project is a part of the Talk to a Teacher project. 108 00:07:47 --> 00:07:53 It is supported by the National Mission on Education through ICT, MHRD,Government of India. 109 00:07:54 --> 00:07:59 More information on this Mission is available at this link http://spoken-tutorial.org/NMEICT-Intro. 110 00:08:00 --> 00:08:01 Animation is done by Udhaya Chandrika. 111 00:08:02 --> 00:08:07 This is Madhuri Ganpathi from IIT Bombay signing off. Thank you for joining.